Aromatics Unit Wastewater Treatment water treatment system in operation
Application 08

Aromatics Unit Wastewater Treatment

BTX-grade wastewater treatment with benzene compliance

Process Overview

What this application solves

Aromatics (BTX) complexes — reforming, extraction, fractionation and isomerization — produce wastewater containing dissolved and free aromatics, extraction solvents (sulfolane, NMP), and oily condensate. Benzene in particular is strictly regulated in both water and air.

WFS combines oil removal, VOC stripping with vapor capture, and biological/adsorption polishing so that treated water meets benzene and COD limits while volatile emissions are controlled.

Application Parameters

Typical influent characteristics

ParameterTypical range
Benzene1 – 200 mg/L
BTEX10 – 1,000 mg/L
COD500 – 10,000 mg/L
Oil & Grease50 – 2,000 mg/L
Solventsvariable mg/L

These ranges frame the design basis. WFS confirms the exact values for your site through laboratory characterization and 24-hour composite sampling, capturing variability across normal, upset and turnaround operation before any equipment is sized.

Benzene
1 – 200 mg/L
BTEX
10 – 1,000 mg/L
COD
500 – 10,000 mg/L
Oil & Grease
50 – 2,000 mg/L
Challenges & Solutions

The problems — and how WFS solves them

Challenges faced
  • Strict benzene limits in water and air
  • Dissolved aromatics & solvents resistant to gravity separation
  • Volatile emissions requiring vapor capture
  • Solvent (sulfolane) degradation products
  • High COD with toxicity to biology
Solutions needed
  • Oil-water separation & flotation
  • Air / steam stripping with vapor-phase carbon
  • Biological treatment acclimated to aromatics
  • Activated carbon polishing for dissolved aromatics
  • Advanced oxidation for refractory solvents
Performance Parameters

Targets the system is designed to meet

Performance parameterDesign target
Benzene< 0.05 – 0.5 mg/L
BTEX removal> 99%
COD removal> 90%
Oil & Grease< 10 mg/L

Guaranteed, tested performance

Every WFS system is commissioned against a documented performance test. We design to the discharge consent, reuse specification or zero-liquid-discharge target — and verify it on site before handover, then sustain it through O&M.

Filtration Approach

Filtration approach & system required

Free oil is removed first, then volatile aromatics are stripped and captured, then residual dissolved organics are biologically oxidized and carbon-polished. Benzene drives the stripper sizing and the air-emission design.

Where extraction solvents persist, advanced oxidation is added to break down refractory compounds before final polishing.

Filtration system required
  • Oil-water separators & flotation
  • VOC stripping tower with off-gas carbon
  • Biological reactor
  • Advanced oxidation unit
  • Activated carbon polishing vessels
Treatment Train

Modular process-train schematic

Treatment Train Schematic Influent Treated
  1. 1Oil Removal
    CPI separator + DAF

    Remove free & emulsified oil

  2. 2VOC Stripping
    Stripper + vapor-phase GAC

    Remove & capture benzene/BTEX

  3. 3Biological
    Acclimated MBBR / activated sludge

    Oxidize dissolved aromatics

  4. 4Advanced Oxidation
    AOP (UV / peroxide / ozone)

    Break refractory solvents

  5. 5Polishing
    Liquid-phase GAC

    Final dissolved-aromatic removal

System Specifications

Indicative system specification

Capacity range
10 – 400 m³/h
Configuration
Skid + basin hybrid
Materials
SS316L / FRP
Off-gas
Carbon / oxidizer, monitored
Automation
PLC/DCS with VOC monitoring
Codes
API, ASME, air-permit compliant
Plant Layout

Layout & general arrangement

Inlet oil removal at grade, the stripping tower and its off-gas carbon block set in a classified area, then biological and polishing units arranged downstream. The AOP unit is placed ahead of final carbon.

Continuous benzene / VOC monitoring is positioned at the stripper and the final outfall.

Inlet ▸General Arrangement — Plot Plan▸ Outlet
  1. 01
    Oil Removal
  2. 02
    VOC Stripping
  3. 03
    Biological
  4. 04
    Advanced Oxidation
  5. 05
    Polishing
Utilities · Chemical Dosing · MCC / Control Room · Sludge Handling · Laboratory
Project Deliverables

What WFS delivers

  1. 1Aromatics wastewater characterization & design basis
  2. 2Benzene compliance & air-emission strategy
  3. 3Stripping, biological & AOP system design
  4. 4Fabrication, delivery & installation
  5. 5E&I, area classification & monitoring
  6. 6Commissioning & benzene/COD performance test
  7. 7O&M, carbon management & training
Delivery Model

From study to continuous O&M

  1. 01
    Study & Assess
  2. 02
    Characterize Water
  3. 03
    Custom Design
  4. 04
    Pilot & Trial
  5. 05
    Detailed Engineering
  6. 06
    Equipment Design
  7. 07
    Fabricate
  8. 08
    Deliver to Site
  9. 09
    Construct
  10. 10
    Electrical & Automation
  11. 11
    Continuous O&M

Discuss your aromatics unit wastewater treatment project

Share your stream data and target specification — WFS will characterize the water and propose a custom train.

Get a Cost-to-Treat Estimate

Share your water chemistry, flow rate and discharge spec — our engineers scope a treatment train and return a tailored, confidential estimate for your site.