Electro-oxidation treatment technology cutaway illustration
Polishing Treatment

Electro-oxidation EO

Chemical-free anodic destruction of refractory organics. Direct anodic oxidation at dimensionally stable electrodes that destroys refractory organics and ammonia in high-salinity brines — chemical-free advanced oxidation.

System Schematic

Representative process-flow — configured to your stream
FEEDSaline Wastewater1. Electrochemical CellBDD / MMO anodes2. Gas SeparationH₂ / O₂ vent3. PolishResidual checkPRODUCTPolished Effluent

Underlying Technology & Scientific Principle

Electro-oxidation (EO) drives current between dimensionally stable anodes (BDD, Ti/IrO₂, Ti/RuO₂) and cathodes immersed in the wastewater. At the anode surface, water is oxidised to hydroxyl radicals and, in chloride-bearing brines, active chlorine species — both attacking organics directly and indirectly.

Working Mechanism

Boron-doped diamond (BDD) anodes give the highest oxidation potential and near-complete mineralisation; mixed-metal-oxide (MMO) anodes are cost-effective for chloride-mediated oxidation. The process simultaneously destroys COD, ammonia (via breakpoint chlorination) and pathogens, with no chemical addition.

Separation / Removal Efficiency

COD removal 70–98%; ammonia removal >95%; >6 log disinfection; mineralisation of PFAS, phenols, dyes and pharmaceuticals demonstrated on BDD.

Operating Principle & Parameters

Current density 100–1000 A/m²; cell voltage 3–10 V; specific energy 5–50 kWh/m³ depending on target; effective across pH 2–10; salinity >1 g/L Cl⁻ enhances efficiency.

Flow Rates & Volumetric Capacities

Stackable electrochemical cells from 1 m³/h pilot to >500 m³/h industrial; modular plate-and-frame or tubular reactor designs.

Fluid Media Compatibility

BDD, Ti/IrO₂, Ti/RuO₂ or Ti/PbO₂ anodes; stainless-steel or Ti cathodes; rectifier and DC power supply; optional gas-collection hood for H₂.

System Schematic & Process Integration

RO concentrate treatment, landfill leachate, produced-water polishing, refinery wastewater, hospital and pharmaceutical effluents.

Options / Variations Available

BDD for full mineralisation; MMO (IrO₂/RuO₂) for chloride-mediated oxidation; PbO₂ for cost-sensitive duties; coupling with UV (photo-electro) or H₂O₂ (electro-Fenton).

System Complexity & Automation Level

High — current/voltage control, conductivity and ORP feedback, polarity reversal for self-cleaning, full SCADA with energy optimisation.

Applications & Performance Delivered

RO concentrate destruction

Mineralises concentrated organics and ammonia in high-salinity brine.

Landfill leachate

Destroys refractory COD and ammonia in a single chemical-free step.

Produced-water polishing

Oxidises residual hydrocarbons and disinfects without biocide addition.

Contaminant Removal Profile

Free Oil >150µmNone
Emulsified OilNone
Suspended SolidsNone
Dissolved SolidsNone
Organics / CODHigh
Dissolved GasesNone
MicrobialsHigh

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