Electrocoagulation treatment technology cutaway illustration
Secondary Treatment

Electrocoagulation EC

In-situ electrochemical coagulation. Electrically dosed coagulation that breaks the toughest stable emulsions and precipitates heavy metals — without bulk chemical addition.

System Schematic

Representative process-flow — configured to your stream
FEEDStable Emulsion1. EC CellAnodic coagulant2. ElectroflotationH₂ bubble lift3. ClarifierFloc / float removalPRODUCTDestabilised WaterMetal-hydroxide Sludge

Underlying Technology & Scientific Principle

Electrocoagulation passes DC current through sacrificial aluminium or iron anodes, electrochemically releasing metal cations that hydrolyse into active coagulant in-situ. These destabilise emulsions and colloids and co-precipitate metals — replacing dosed alum/ferric with electrically generated coagulant.

Working Mechanism

In the EC cell, anodic dissolution generates Al³⁺/Fe²⁺ that form hydroxide flocs, while cathodic hydrogen micro-bubbles provide simultaneous electroflotation. Destabilised oil, colloids and metal hydroxides aggregate and are removed by flotation and/or downstream clarification.

Separation / Removal Efficiency

Removes 90–99% of emulsified oil, fine TSS and heavy metals (As, Cr, Pb, Zn) and reduces COD; particularly effective on chemically stable, surfactant-laden emulsions resistant to conventional chemistry.

Operating Principle & Parameters

Current density 10–150 A/m²; residence 2–10 min; conductivity-dependent power. Anode passivation managed by polarity reversal and periodic cleaning; sacrificial plates consumed over time.

Flow Rates & Volumetric Capacities

Modular cells from 1 to 200+ m³/h; stacked plate packs scale throughput. Compact, skid-mounted.

Fluid Media Compatibility

Aluminium or iron electrode plates in non-conductive cells; rectifier and control panel. Suited to saline, oily, metal-bearing wastewater.

System Schematic & Process Integration

Secondary treatment after primary de-oiling, ahead of flotation/clarification, media filtration and membranes; an alternative or complement to chemical coagulation/DAF.

Options / Variations Available

Al vs. Fe electrodes; monopolar vs. bipolar stacks; integrated electroflotation; reversing-polarity anti-passivation control.

System Complexity & Automation Level

Moderate–high — current/voltage regulation on conductivity and load, automated polarity reversal and plate-wear monitoring via PLC.

Applications & Performance Delivered

Stable emulsion breaking

Treats surfactant-stabilised oily water that resists chemical demulsifiers.

Heavy-metal removal

Precipitates dissolved metals to discharge limits.

Frac-flowback & desalter brine

Reduces oil, solids and metals in complex high-strength streams.

Contaminant Removal Profile

Free Oil >150µmMedium
Emulsified OilHigh
Suspended SolidsHigh
Dissolved SolidsLow
Organics / CODMedium
Dissolved GasesNone
MicrobialsMedium

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